Overview of project A08
Non-Equilibrium Dynamics of Tunnel Junctions Excited with Terahertz Light
Investigation of individual atoms, molecules, and clusters using scanning tunnelling microscopy has been allowing deep understanding of physical and chemical effects taking place at the atomic scale. Yet, many microscopic processes, such as charge transfer, vibration, and conformational switching of molecules, often take place at timescales that are out-of-reach for conventional microscopes. The coupling of terahertz light to the junction of a scanning tunnelling microscope (THz-STM) appears to solve this issue, with recent demonstrations of a sub-picosecond time resolution on individual molecules. The technique unravels unprecedented investigations of fast processes at the atomic scale. The main goals of the project are a further understanding of the microscopic processes associated with this young technique and the exploration of non-equilibrium dynamics of individual metal clusters and molecules adsorbed on surfaces.
Figure: Illustration of the instrumentation working principle of THz-STM.
Publications
2024
Hüseyin Azazoglu, Philip Kapitza, Martin Mittendorff, Rolf Möller and Manuel Gruber
Variable-Temperature Lightwave-Driven Scanning Tunneling Microscope With a Compact, Turn-Key Terahertz Source
Rev. Sci. Instrum. 95, 023703 (2024)
DOI: 10.1063/5.0165719
Hüseyin Azazoglu, Rolf Möller and Manuel Gruber
Thermal Expansion in Photo-Assisted Tunneling: Visible Light versus Free-Space Terahertz Pulses
Surf. Sci. 743, 122465 (2024)
DOI: 10.1016/j.susc.2024.122465
Sven Johannsen, Roberto Robles, Alexander Weismann, Karl Ridier, Richard Berndt and Manuel Gruber
Spin‐State Switching of Spin‐Crossover Complexes on Cu(111) Evidenced by Spin‐Flip Spectroscopy
Angew. Chen. Int. Ed., e202411865 (2024)
DOI: 10.1002/anie.202411865
Chao Li, Marie-Laure Bocquet, Yan Lu, Nicolas Lorente, Manuel Gruber, Richard Berndt and Alexander Weismann
Large Orbital Moment and Dynamical Jahn-Teller Effect of AlCl-Phthalocyanine on Cu(100)
Phys. Rev. Lett.133, 126201 (2024)
DOI: 10.1103/PhysRevLett.133.126201
Nicolás Montenegro‐Pohlhammer, Rocío Sánchez‐de‐Armas, Manuel Gruber and Carmen J. Calzado
Mechanisms for the Spin‐State Switching of Strapped Ni‐Porphyrin Complexes Deposited on Metal Surfaces: Insights from Quantum Chemical Calculations
small 133, 2406313 (2024)
DOI: 10.1002/smll.202406313
Manuel Gruber
Oberflächlich geschaltet: Verschiedene Spinzustände einzelner Moleküle an Oberflächen lassen sich gezielt schalten und für unterschiedliche Anwendungen nutzen
Vakuum in Forschung und Praxis 36, 23 (2024)
DOI: 10.1002/vipr.202400822
Lea Kämmerer, Gérald Kämmerer, Manuel Gruber, Jan Grunwald, Tobias Lojewski, Laurent Mercadier, Loïc Le Guyader, Robert Carley, Cammille Carinan, Natalia Gerasimova, David Hickin, Benjamin E. Van Kuiken, Giuseppe Mercurio, Martin Teichmann, Senthil Kumar Kuppusamy, Andreas Scherz, Mario Ruben, Klaus Sokolowski-Tinten, Andrea Eschenlohr, Katharina Ollefs, Carolin Schmitz-Antoniak, Felix Tuczek, Peter Kratzer, Uwe Bovensiepen and Heiko Wende
Femtosecond Spin-State Switching Dynamics of Fe(II) Complexes Condensed in Thin Films
136, (2024)
DOI: 10.1021/acsnano.4c05123
2023
Jan Grunwald, Jorge Torres, Axel Buchholz, Christian Näther, Lea Kämmerer, Manuel Gruber, Sebastian Rohlf, Sangeeta Thakur, Heiko Wende, Winfried Plass, Wolfgang Kuch and Felix Tuczek
Defying the Inverse Energy Gap Law: A Vacuum-Evaporable Fe(ıı) Low-Spin Complex with a Long-Lived LIESST State
Chem. Sci. 26, 7361 (2023)
DOI: 10.1039/d3sc00561e
Chao Li, Roberto Robles, Nicolas Lorente, Sanjoy Kr Mahatha, Sebastian Rohlf, Kai Rossnagel, Alessandro Barla, Boris V. Sorokin, Stefano Rusponi, Philippe Ohresser, Sara Realista, Paulo N. Martinho, Torben Jasper-Toennies, Alexander Weismann, Richard Berndt and Manuel Gruber
Large Orbital Moment of Two Coupled Spin-Half Co Ions in a Complex on Gold
ACS Nano 17, 10608 (2023)
DOI: 10.1021/acsnano.3c01595
Sven Johannsen, Manuel Gruber, Cyrille Barreteau, Maksym Seredyuk, José Antonio Real, Troels Markussen and Richard Berndt
Spin-Crossover and Fragmentation of Fe(neoim)2 on Silver and Gold
J. Phys. Chem. Lett. 14, 7814 (2023)
DOI: 10.1021/acs.jpclett.3c01551
Kira Kolpatzeck, Lothar Brendel, Rolf Möller, Roberto Robles and Nicolás Lorente
Paradoxical Effects for a One-Dimensional Periodic Potential Embedded in a Two-Dimensional System
Phys. Rev. B 107, 155418 (2023)
DOI: 10.1103/PhysRevB.107.155418
2022
Sven Johannsen, Sascha Ossinger, Jan Grunwald, Alexander Herman, Heiko Wende, Felix Tuczek, Manuel Gruber and Richard Berndt
Spin Crossover in a Cobalt Complex on Ag(111)
Angew. Chem. Int. Ed. 61, e202115892 (2022)
DOI: 10.1002/anie.202115892