CRC/TRR 247 - 1st funding period 2018-2022

At the University of Duisburg-Essen and the Ruhr-University Bochum.
With Participation of: Max Planck Institute for Chemical Energy Conversion, Max-Planck-Institut für Kohlenforschung, and Fritz Haber Institute of the Max Planck Society

Publications

Selected publications within CRC/TRR 247

2022

Budiyanto, E., Salamon, S., Wang, Y., Wende, H., Tüysüz, H.: Phase Segregation of Cobalt Iron Oxide Nanowires Towards Enhanced Oxygen Evolution Reaction Activity. JACS Au, 2022, 2, 3, 697-710. DOI: 10.1021/jacsau.1c00561.
Exner, K. S.: Rapid Screening of Mechanistic Pathways for Oxygen-Reduction Catalysts. ChemCatChem, 2022, e202201222. DOI: 10.1002/cctc.202201222
Exner, K. S.: Blickpunkt Nachwuchs: Theoretische Elektrokatalyse. Nachrichten aus der Chemie 2022, 70, 82-84. DOI: 10.1002/nadc.20224125416.
Geiss, J., Falk, T., Ognjanovic, S., Anke, S., Peng, B., Muhler, M., Winterer, M.: Atom Pair Frequencies as a Quantitative Structure–Activity Relationship for Catalytic 2-Propanol Oxidation over Nanocrystalline Cobalt–Iron–Spinel. J. Phys. Chem. C, 2022, 126, 25, 10346–10358. DOI: 10.1021/acs.jpcc.2c00788.
He, T., Exner, K. S.: Computational Electrochemistry Focusing on Nanostructured Catalysts: Challenges and Opportunities. Mater. Today Energy, 2022, 28, 101083. DOI: 10.1016/j.mtener.2022.101083.
Jaugstetter, M., Blanc, N., Kratz, M., Tschulik, K.: Electrochemistry under Confinement. Chem. Soc. Rev. 2022, 51, 2491-2543. DOI: 10.1039/D1CS00789K.
Kenmoe, S., Douma, D.H., Raji, A.T., M’Passi-Mabiala, B., Götsch, T., Girgsdies, F., Knop-Gericke, A., Schlögl, R., Spohr, E.: X-ray Absorption Near-Edge Structure (XANES) at the O K-Edge of Bulk Co₃O₄: Experimental and Theoretical Studies. J. Nanomater. 2022, 12, 921. DOI: 10.3390/nano12060921.
Klein, J., Kampermann, L., Korte, J., Dreyer, M., Budiyanto, E., Tüysüz, H., Ortega, K. F., Behrens, M., Bacher, G.: Monitoring Catalytic 2‑Propanol Oxidation over Co₃O₄ Nanowires via In Situ Photoluminescence Spectroscopy. J. Phys. Chem. Lett. 2022, 13, 3217. DOI: 10.1021/acs.jpclett.2c00098.
Moon, G., Wang, Y., Kim, S., Budiyanto, E., Tüysüz, H.: Preparation of Practical High-Performance Electrodes for Acidic and Alkaline Media Water Electrolysis. ChemSusChem 2022, 15, e202102114. DOI: 10.1002/cssc.202102114.
Priamushko, T., Budiyanto, E., Eshraghi, N., Weidenthaler, C., Kahr, J., Hahn, M., Tüysüz, H., Kleitz, F.: Incorporation of Cu/Ni in ordered mesoporous Co-based spinels to facilitate oxygen evolution and reduction reactions in alkaline media and aprotic Li-O₂ batteries. ChemSusChem 2022, 15, e202102404. DOI: 10.1002/cssc.202102404.
Razzaq, S., Exner, K.S.: Method to Determine the Bifunctional Index for the Oxygen Electrocatalysis from Theory. ChemElectroChem 2022, 9, e202101603. DOI: 10.1002/celc.202101603.
Razzaq, S., Exner, K.S.: Statistical Analysis of Breaking Scaling Relation in the Oxygen Evolution Reaction. Electrochim. Acta 2022, 412, 140125. DOI: 10.1016/j.electacta.2022.140125.
Rushiti, A., Falk, T., Muhler, M., Haettig, C.: Interactions of Water and Short-Chain Alcohols with CoFe₂O₄ (001) Surfaces at Low Coverages. Phys. Chem. Chem. Phys. 2022. accepted. DOI: 10.1039/D2CP02480B .
Saw, E.N., Kanokkanchana, K., Amin, H.M.A., Tschulik, K.: Unravelling Anion Solvation in Water-Alcohol Mixtures by Single Entity Electrochemistry. ChemElectroChem 2022, e202101435. DOI: 10.1002/celc.202101435.
Xiang, W., Yang, N., Li, X., Linnemann, J., Hagemann, U., Ruediger, O., Heidelmann, M., Falk, T., Aramini, M., DeBeer, S., Muhler, M., Tschulik, K., Li, T.: 3D atomic-scale imaging of mixed Co-Fe spinel oxide nanoparticles during oxygen evolution reaction. Nat. Commun. 2022, 13, 179. DOI: 10.1038/s41467-021-27788-2.
Zerebecki, S., Salamon, S., Lander, J., Yang, Y., Tong, Y., Budiyanto, E., Waffel. D., Dreier, M., Saddeler, S., Kox, T., Kenmoe, S., Spohr, E., Schulz, S., Behrens, M., Muhler, M., Tüysüz, H., Campen, R.K., Wende, H., Reichenberger, S., Barcikowski, S.: Engineering of Cation Occupancy of CoFe₂O₄ Oxidation Catalysts by Nanosecond, Single-Pulse Laser Excitation in Water. ChemCatChem 2022, 14, e202101785. DOI: 10.1002/cctc.202101785.

2021

Andronescu, C., Masa, J., Tilley, R.D., Gooding, J.J., Schuhmann, W.: Electrocatalysis in confined space. Curr. Opin. Electrochem. 2021, 25, 100644. DOI: 10.1016/j.coelec.2020.100644.
Bähr, A., Petersen, H., Tüysüz, H.: Large scale production of carbon supported cobalt-based functional nanoparticles for oxygen evolution reaction, ChemCatChem. 2021. DOI: 10.1002/cctc.202100594.
Bera, A., Bullert, D., Linke, M., Hasselbrink, E.: Vibrational Sum Frequency Spectroscopy Study of Alcohol Adsorption on Thin-Film TiO₂ at Ambient Pressure and Temperature. J. Phys. Chem. C. 2021. DOI: 10.1021/acs.jpcc.1c01603.
Budiyanto, E., Zerebecki, S., Weidenthaler, C., Kox, T., Kenmoe, S., Spohr, E., DeBeer, S., Rüdiger, O., Reichenberger, S., Barcikowsi, S., Tüysüz, H.: Impact of single-pulse, low-intensity laser post-processing on structure and activity of mesostructured cobalt oxide for oxygen evolution reaction. ACS App. Mater. Interfaces. 2021. DOI: 10.1021/acsami.1c08034.
Chee, S.W., Lunkenbein, T., Schlögl, R., Cuenya, B.R.: In situ and operando electron microscopy in heterogeneous catalysis-insights into multi-scale chemical dynamics. J. Phys.: Condens. Matter 2021, 33, 153001. DOI: 10.1088/1361-648X/abddfd .
Dreyer, M., Krebs, M., Najafishirtari, S., Rabe, A., Ortega, K.F., Behrens, M.: The Effect of Co Incorporation on the CO Oxidation Activity of LaFe_1-xCo_xO₃ Perovskites. Catalysts 2021, 11 (5), 550. DOI: 10.3390/catal11050550.
Exner, K.S.: The Electrochemical-Step Asymmetry Index. MethodsX 2021, 8, 101590. DOI: 10.1016/j.mex.2021.101590.
Exner, K.S.: On the lattice oxygen evolution mechanism: Avoiding pitfalls. ChemCatChem 2021, 13, 4066-4074. DOI: 10.1002/cctc.202101049.
Exner, K.S.: Why the optimum thermodynamic free-energy landscape of the oxygen evolution reaction reveals an asymmetric shape. Mater. Today Energy 2021, 21, 100831. DOI: 10.1016/j.mtener.2021.100831 .
Exner, K.S.: Why the breaking of the OOH versus OH scaling relation might cause decreased electrocatalytic activity. Chem. Catal. 2021, 1 (2), 258. DOI: 10.1016/j.checat.2021.06.011.
Exner, K.S.: Boosting the Stability of RuO₂ in the Acidic Oxygen Evolution Reaction by Tuning Oxygen-Vacancy Formation Energies: A Viable Approach Beyond Noble-Metal Catalysts? ChemElectroChem 2021, 8, 46-48. DOI: 10.1002/celc.202001465.
Exner, K.S.: Why approximating electrocatalytic activity by a single free-energy change is insufficient. Electrochim. Acta 2021, 375, 137975. DOI: 10.1016/j.electacta.2021.137975.
Exner, K.S.: Why the Microkinetic Modeling of Experimental Tafel Plots Requires Knowledge of the Reaction Intermediate’s Binding Energy. Electrochem. Sci Adv. 2021. DOI: 10.1002/elsa.202100037.
Falk, T., Anke, S., Hajiyani, H., Saddeler, S., Schulz, S., Pentcheva, R., Peng, B., Muhler, M.: Influence of the Particle Size on Selective 2-Propanol Gas-Phase Oxidation over Co₃O₄ Nanospheres. Catalysis Science and Technology. (accepted). DOI: 10.1039/D1CY00944C.
Falk, T., Budiyanto, E., Dreyer, M., Pflieger, C., Waffel, D., Büker, J., Weidenthaler, C., Ortega, K.F., Behrens, M., Tüysüz, H., Muhler, M., Peng, B.X.: Identification of Active Sites in the Catalytic Oxidation of 2-Propanol over Co_1+xFe_2-xO₄ Spinel Oxides at Solid/Liquid and Solid/Gas Interfaces. ChemCatChem 2021. DOI: 10.1002/cctc.202100352.
Füngerlings, A., Koul, A., Dreyer, M., Rabe, A., Morales, D.M., Schuhmann, W., Behrens, M., Pentcheva, R.: Synergistic Effects of Co and Fe on the OER activity of LaCo_xFe_1−xO₃. Chemistry - A European Journal 2021. (in press). DOI: 10.1002/chem.202102829.
Hammad, M., Fortugno, P., Hardt, S., Kim, C., Salamon, S., Schmidt, T. C., Wende, H., Schulz, C., Wiggers, H.: Large-scale synthesis of iron oxide/graphene hybrid materials as highly efficient photo-Fenton catalyst for water remediation. Environmental Technology & Innovation 2021, 21, 101239. DOI: 10.1016/j.eti.2020.101239.
Hartwig, C., Schweinar, K., Jones, T.E., Beeg, S., Schmidt, F.P., Schlögl, R., Greiner, M.: Isolated Pd atoms in a silver matrix: Spectroscopic and chemical properties, J. Chem. Phys. 2021, 154 (18), 184703. DOI: 10.1063/5.0045936.
Heese-Gärtlein, J., Rabe, A., Behrens, M.: Challenges in the Application of Manganese Oxide Powders as OER Electrocatalysts: Synthesis, Characterization, Activity and Stability of Nine Different Mn_xO_y Compounds. ZAAC 2021. DOI: 10.1002/zaac.202000180.
Jeon, H.S., Timoshenko, J., Rettenmaier, C., Herzog, A., Yoon, A., Chee, S.W., Oener, S., Hejral, U., Haase, F.T., Roldan Cuenya, B.: Selectivity control of Cu nanocrystals in a gas-fed flow cell through CO₂ pulsed electroreduction. J. Am. Chem. Soc. 2021, 143(19), 7578-7587. DOI: 10.1021/jacs.1c03443.
Kampermann, L., Klein, J., Korte, J., Kowollik, O., Pfingsten, O., Smola, T., Saddeler, S., Piotrowiak, T. H., Salamon, S., Landers, J., Wende, H., Ludwig, A., Schulz, S., Bacher, G.: Link between Structural and Optical Properties of Co_xFe_3-xO₄ Nanoparticles and Thin Films with Different Co/Fe Ratios. J. Phys. Chem. C 2021, 125 (26), 14356-14365. DOI: 10.1021/acs.jpcc.0c11277.
Klein, J., Kampermann, L., Saddeler, S., Korte, J., Kowollik, O., Smola, T., Schulz, S., Bacher, G.: Atmosphere-sensitive photoluminescence of CoxFe_3-xO₄ metal oxide nanoparticles. RSC Adv. 2021, 11, 33905-33915. DOI: 10.1039/D1RA06228J.
Klemenz, S., Stegmüller, A., Yoon, S., Felser, C., Tüysüz, H., Weidenkaff, A.: Holistic view on materials development: Water electrolysis as a case study. Angew. Chem. Int. Ed. 2021. DOI: 10.1002/anie.202105324.
Kortewille, B., Pfingsten, O., Bacher, G., Strunk, J.: Supported Vanadium Oxide as a Photocatalyst in the Liquid Phase: Dissolution Studies and Selective Laser Excitation. ChemPhotoChem, 2021, 5, 1-8. DOI: doi.org/10.1002/cptc.202100120.
Lange, T., Reichenberger, S., Rohe, M., Bartsch, M., Kampermann, L., Klein, J., Strunk, J., Bacher, G., Schlögl, R., Barcikowski, S: Alumina-Protected, Durable and Photostable Zinc Sulfide Particles from Scalable Atomic Layer Deposition. Adv. Funct. Mater. 2021, 2009323. DOI: 10.1002/adfm.202009323.
Linnemann, J., Kanokkanchana, K., Tschulik, K.: Design Strategies for Electrocatalysts from an Electrochemist’s Perspective. ACS Catal. 2021, 5318-5346. DOI: 10.1021/acscatal.0c04118.
Liu, Y.,Peng, Y., Naschitzki, M., Gewinner, S., Schöllkopf, W., Kuhlenbeck, H., Pentcheva, R., Roldan Cuenca, B.: Surface oxygen vacancies on reduced Co₃O₄(100): Superoxide formation and ultra-low-temperature CO oxidation. Angew. Chem. Int. Ed. 2021, 60, 2–9. DOI: 10.1002/anie.202103359.
Liu, Z., Corva, M., Amin, H.M.A., Blanc, N., Linnemann, J., Tschulik, K.: Single Co₃O₄ Nanocubes Electrocatalyzing the Oxygen Evolution Reaction: Nano-Impact Insights into Intrinsic Activity and Support Effects. Int. J. Mol. Sci. 2021, 22, 13137. DOI: 10.3390/ijms222313137.
Najafishirtari, S., Ortega, K.F., Douthwaite, M., Pattisson, S., Hutchings, G.J., Bondue, C.J., Tschulik, K., Waffel, D., Peng, B., Deitermann, M., Busser, G.W., Muhler, M., Prof. Behrens, M.: Frontispiece: A Perspective on Heterogeneous Catalysts for the Selective Oxidation of Alcohols. Chem. Eur. J. 2021, 27, 16809. DOI: 10.1002/chem.202186861.
Ooka, H., Huang, J., Exner, K.S.: The Sabatier Principle in Electrocatalysis: Basics, Limitations, and Extensions. Front. Energy Res. 2021, 9, 654460. DOI: 10.3389/fenrg.2021.654460.
Öztürk, S., Moon, G-H., Spieß, A., Budiyanto, E., Roitsch, S., Tüysüz, H., Janiak, C.: A highly-efficient oxygen evolution electrocatalyst derived from a metal-organic framework and Ketjenblack carbon material. ChemPlusChem 2021. DOI: 10.1002/cplu.202100278.
Peng, Y., Hajiyani, H., Pentcheva, R.: Influence of Fe and Ni doping on the OER performance at the Co₃O₄(001): Insights from DFT+U calculations. ACS Catalysis 2021, 11, 5601–5613. DOI: 10.1021/acscatal.1c00214.
Rushiti, A., Hättig, C.: Activation of Molecular O₂ on CoFe₂O₄ (001) Surfaces: An Embedded Cluster Study. Chem. Eur. J. (accepted). DOI: 10.1002/chem.202102784
Rushiti, A., Hättig, C., Wen, B., Selloni, A.: Structure and Reactivity of Pristine and Reduced Spinel CoFe₂O₄ (001)/(100) Surfaces. J. Phys. Chem. C 2021. DOI: 10.1021/acs.jpcc.1c01881.
Saddeler, S., Bendt, G., Salamon, S., Haase, F., Landers, J., Timoshenko, J., Rettenmaier, C., Jeon, H.S., Bergmann, A., Wende, H., Roldán Cuenya, B., Schulz, S.: Influence of the cobalt content in cobalt iron oxides on the electrocatalytic OER activity. J. Mater. Chem. A 2021 (accepted). DOI: 10.1039/D1TA06568H.
Shen, Z., Hu, Y., Li, BF., Zou, YT., Li, SJ, Busser, G.W., Wang, X., Zhao, G., Muhler, M.: State-of-the-art progress in the selective photo-oxidation of alcohols. Journal of Energy Chemistry 2021, 62, 338–350. DOI: 10.1016/j.jechem.2021.03.033.
Quast, T., Varhade, S., Saddeler, S., Chen, Y.-T., Andronescu, C., Schulz, S., Schuhmann, W.: Single Particle Nanoelectrochemistry Reveals the Catalytic Oxygen Evolution Reaction Activity of Co3O4 Nanocubes. Angew. Chem. Int. Ed. 2021. (accepted). DOI: 10.1002/anie.202109201 .
Yu, M., Budiyanto, E., Tüysüz, H.: Principle of water electrolysis and recent progress of nickel, cobalt and iron-based oxides for oxygen evolution reaction. Angew. Chem. Int. Ed. 2021. DOI: 10.1002/anie.202103824.
Yu, M., Li, G., Fu, C., Liu, E., Manna, K., Budiyanto, E., Yang, Q., Felser, C., Tüysüz, H.: Tunable e_g Orbital Occupancy in Heusler Compounds for Oxygen Evolution Reaction. Angew. Chem. Int. Ed. 2021, 60, 1 – 7. DOI: 10.1002/anie.202013610.
Zhang, J., He, WH., Aiyappa, H.B., Quast, T., Dieckhofer, S., Ohl, D., Junqueira, J.R.C., Chen, YT., Masa, J., Schuhmann, W.: Hollow CeO₂@Co₂N Nanosheets Derived from Co-ZIF-L for Boosting the Oxygen Evolution Reaction. Adv. Mater. Interfaces 2021, 2100041. DOI: 10.1002/admi.202100041.
Zhao, GX., Bonke, S.A., Schmidt, S., Wang, Z., Hu, B., Falk, T., Hu, YZ., Rath, T., Xia, W., Peng, BX., Schnegg, A., Weng, YX., Muhler, M.: Highly Efficient and Selective Aerobic Oxidation of Cinnamyl Alcohol under Visible Light over Pt-Loaded NaNbO₃ Enriched with Oxygen Vacancies by Ni Doping. ACS Sustainable Chem. Eng. 2021, 9, 15, 5422–5429. DOI: 10.1021/acssuschemeng.1c00460.

2020

Alkan, B., Medina, D., Landers, J., Heidelmann, M., Hagemann, U., Salamon, S., Andronescu, C., Wende, H., Schulz, C., Schuhmann, W., Wiggers, H.: Spray-Flame-Prepared LaCo_1–xFe_xO₃ Perovskite Nanoparticles as Active OER Catalysts: Influence of Fe Content and Low-Temperature Heating, ChemElectroChem 2020. DOI: 10.1002/celc.201902051.
Amendola, V., Amans, D., Ishikawa, Y., Koshizaki, N., Scirè, S., Compagnini, G., Reichenberger, S., Barcikowski, S.: Room-temperature laser synthesis in liquid of oxide, metal-oxide core-shells and doped oxide nanoparticles, Chem. Eur. J. 2020. DOI: 10.1002/chem.202000686.
Anke, S., Falk, T., Bendt, G., Sinev, I., Zegkinoglou, I., Jeon, H., Roldan Cuenya, B., Schulz, S., Muhler, M.: On the Reversible Deactivation of Cobalt Ferrite Spinel Nanoparticles applied in Selective 2-Propanol Oxidation, Journal of Catalysis 2020, 382, 57-68. DOI: 10.1016/j.jcat.2019.12.007.
Bera, A., Bullert, D., Hasselbrink, E.: Vibrational Sum Frequency Spectroscopy Study of Methanol Adsorption on Thin Film TiO₂ at Ambient Pressure and Temperature, The Journal of Physical Chemistry C 2020. DOI: 10.1021/acs.jpcc.0c05499.
Blanc, N., Rurainsky, C., Tschulik, K.: Implications of resistance and mass transport limitations on the common Tafel approach at composite catalyst thin-film electrodes, Journal of Electroanalytical Chemistry 2020, 872, SI 114345. DOI: 10.1016/j.jelechem.2020.114345.
Budiyanto, E., Yu, MQ., Chen, MM., DeBeer, S., Rüdiger, O., Tüysüz, H.: Tailoring Morphology and Electronic Structure of Cobalt Iron Oxide Nanowires for Electrochemical Oxygen Evolution Reaction, ACS Applied Energy Materials 2020, 3 (9), 8583-8594. DOI: 10.1021/acsaem.0c01201.
Büker, J., Alkan, B., Fu, Q., Xia, W., Schulwitz, J., Waffel, D., Falk, T., Schulz, C., Wiggers, H., Muhler, M., Peng, BX.: Selective cyclohexene oxidation with O₂, H₂O₂ and tert-butyl hydroperoxide over spray-flame synthesized LaCo_1-xFe_xO₃nanoparticles, Catalysis Science & Technology 2020, 10 (15), 5196-5206. DOI: 10.1039/d0cy00906g.
Dai, Y., Poidevin, C., Ochoa-Hernández, C., Auer, A.A., Tüysüz, H.: A Supported Bismuth Halide Perovskite Photocatalyst for Selective Aliphatic and Aromatic C-H Bond Activation, Angewandte Chemie International Edition 2020. DOI: 10.1002/anie.201915034.
Dionigi, F., Zeng, ZH., Sinev, I., Merzdorf, T., Deshpande, S., Lopez, M.B., Kunze, S., Zegkinoglou, I., Sarodnik, H., Fan, DX., Bergmann, A., Drnec, J., de Araujo, J.F., Gliech, M., Teschner, D., Zhu, J., Li, WX., Greeley, J., Cuenya, B.R., Strasser, P.: In-situ structure and catalytic mechanism of NiFe and CoFe layered double hydroxides during oxygen evolution, Nature Communications 2020. DOI: 10.1038/s41467-020-16237-1.
Dubey, A., Castillo, M.E., Landers, J., Salamon, S., Wende, H., Hagemann, U., Gemeiner, P., Dkhil, B., Shvartsman, V.V., Lupascu, D.C.: Effect of Mn and Ba Codoping on a Magnetic Spin Cycloid of Multiferroic Bismuth Ferrite Nanoparticles, J. Phys. Chem. C 2020, 124, 40, 22266–22277. DOI: 10.1021/acs.jpcc.0c05778.
Exner, K. S.: A Universal Descriptor for the Screening of Electrode Materials for Multiple-Electron Processes: Beyond the Thermodynamic Overpotential, ACS Catalysis 2020, 10, 12607–12617. DOI: 10.1021/acscatal.0c03865.
Fan, XL., Zerebecki, S., Du, R., Hubner, R., Marzum, G., Jiang, GC., Hu, Y., Barcikowki, S., Reichenberger, S., Eychmuller, A.: Promoting the Electrocatalytic Performance of Noble Metal Aerogels by Ligand-Directed Modulation, Angewandte Chemie International Edition 2020. DOI: 10.1002/anie.201913079.
Fertman, E.L., Fedorchenko, A.V., Desnenko, V.A., Shvartsman, V.V., Lupascu, D.C., Salamon, S., Wende, H., Vaisburd, A.I., Stanulis, A., Ramanauskas, R., Olekhnovich, N.M., Pushkarev, A.V., Radyush, Y.V., Khalyavin, D.D., Salak, A.N.: Exchange bias effect in bulk multiferroic BiFe_0.5Sc_0.5O₃, AIP Advances 2020, 10, 045102. DOI: 10.1063/1.5135586.
Hähsler, M., Landers, J., Nowack, T., Salamon, S., Zimmermann, M., HeiBler, S., Wende, H., Behrens, S.: Magnetic Properties and Mossbauer Spectroscopy of Fe₃O₄/CoFe₂O₄ Nanorods, Inorganic Chemistry 2020, 59 (6), 3677-3685. DOI: 10.1021/acs.inorgchem.9b03267.
Hajiyani, H., Pentcheva, R.: Influence of 3d, 4d, and 5d dopants on the oxygen evolution reaction at α-Fe₂O₃(0001) under dark and illumination conditions, The Journal of Chemical Physics 2020, 152, 124709. DOI: 10.1063/1.5143236.
Hammad, M., Hardt, S., Slabu, I., Salamon, S., Landers, J., Wende, H., Schulz, C., Wiggers, H.: Gas phase synthesis of small iron oxide nanoparticles for improved magnetic hyperthermia performance, Journal of Alloys and Compounds 2020, 824, 153814. DOI: 10.1016/j.jallcom.2020.153814.
Heese-Gärtlein, J., Morales, D.M., Rabe, A., Bredow, T., Schuhmann, W., Behrens, M.: Factors Governing the Activity of alpha-MnO(2)Catalysts in the Oxygen Evolution Reaction: Conductivity versus Exposed Surface Area of Cryptomelane, Chemistry-A European Journal 2020, 26 (53), 12256-12267. DOI: 10.1002/chem.201905090.
Hein, D., Wartner, G., Bergmann, A., Bernal, M., Roldan Cuenya, B., Seidel, R.: Reversible Water-Induced Phase Changes of Cobalt Oxide Nanoparticles, ACS Nano 2020, 14, 11, 15450–15457. DOI: 10.1021/acsnano.0c06066.
Hupfeld, T., Stein, F., Barcikowski, S., Gökce, B., Wiedwald, U.: Manipulation of the Size and Phase Composition of Yttrium Iron Garnet Nanoparticles by Pulsed Laser Post-Processing in Liquid, Molecules 2020, 25 (8), 1869. DOI: 10.3390/molecules25081869.
Kazakova, M.A., Morales, D.M., Andronescu, D., Elumeeva, K., Selyutin, A.G., Ishchenko, A.V., Golubtsov, G.V., Dieckhöfer, S., Schuhmann, W., Masa, J.: Fe/Co/Ni mixed oxide nanoparticles supported on oxidized multi-walled carbon nanotubes as electrocatalysts for the oxygen reduction and the oxygen evolution reactions in alkaline media, Catalysis Today 2020, 357, 259-268. DOI: 10.1016/j.cattod.2019.02.047.
Kox, T., Spohr, E., Kenmoe, S.: Impact of Solvation on the Structure and Reactivity of the Co₃O₄ (001)/H₂O Interface: Insights From Molecular Dynamics Simulations. Frontiers in Energy Research 2020, 8:604799. DOI: 10.3389/fenrg.2020.604799.
Liu, ZB., Li, SF., Yang, J., Tan, XY., Yu, C., Zhao, CT., Han, XT., Huang, HW., Wan, G., Liu, YJ., Tschulik, K., Qin, JS.: Ultrafast Construction of Oxygen-Containing Scaffold over Graphite for Trapping Ni²⁺ into Single Atom Catalysts, ACS Nano 2020, 14 (9), 11662-11669. DOI: 10.1021/acsnano.0c04210.
Masa, J., Andronescu, C., Schuhmann, W.: Electrocatalysis as the Nexus for Sustainable Renewable Energy: The Gordian Knot of Activity, Stability, and Selectivity, Angewandte Chemie International Edition 2020, 59 (36), 15298-15312. DOI: 10.1002/anie.202007672.
Möller, S., Barwe, S., Masa, J., Wintrich, D., Seisel, S., Baltruschat, H., Schuhmann, W.: Online Monitoring of Electrochemical Carbon Corrosion in Alkaline Electrolytes by Differential Electrochemical Mass Spectrometry, Angewandte Chemie International Edition 2020, 58, 1-6. DOI: 10.1002/anie.201909475
Penner, S., Götsch, T., Klötzer, B.: Increasing Complexity Approach to the Fundamental Surface and Interface Chemistry on SOFC Anode Materials, Accounts of Chemical Research 2020, 53 (9), 1811-1821. DOI: 10.1021/acs.accounts.0c00218.
Piotrowiak, T.H., Wang, X., Banko, L., Kumari, S., Sarker, S., Mehta, A., Ludwig, A.: High-Throughput Characterization of (Fe_xCo_1-x)₃O₄ Thin-Film Composition Spreads, ACS Combinatorial Science 2020, 22 (12), 804-812. DOI: 10.1021/acscombsci.0c00126.
Priamushko, T., Guillet-Nicolas, R., Yu, MQ., Doyle, M., Weidenthaler, C., Tüysüz, H., Kleitz, F.: Nanocast Mixed Ni-Co-Mn Oxides with Controlled Surface and Pore Structure for Electrochemical Oxygen Evolution Reaction, ACS Appl. Energy Mater. 2020, 3, 5597−5609. DOI: 10.1021/acsaem.0c00544.
Quast, T., Aiyappa, H.B., Saddeler, S., Wilde, P., Chen, Y.T., Schulz, S., Schuhmann, W.: Single entity electrocatalysis of individual ‘picked‐and‐dropped’ Co₃O₄ nanoparticles on the tip of a carbon nanoelectrode, Angewandte Chemie International Edition 2020. DOI: 10.1002/anie.202014384.
Saddeler, S., Hagemann, U., Schulz, S.: Effect of the Size and Shape on the Electrocatalytic Activity of Co₃O₄ Nanoparticles in the Oxygen Evolution Reaction, Inorg. Chem. 2020. DOI: 10.1021/acs.inorgchem.0c0118.
Scherrer, B., Li, T., Tsyganok, A., Döbeli, M., Gupta, B., Malviya, K.D., Kasian, O., Maman, N., Gault, B., Grave, D.A., Mehlman, A., Visoly-Fisher, I., Raabe, D., Rothschild, A.: Defect Segregation and Its Effect on the Photoelectrochemical Properties of Ti-Doped Hematite Photoanodes for Solar Water Splitting, Chemistry of Materials 2020. DOI: 10.1021/acs.chemmater.9b03704.
Tarnev, T., Cychy, S., Andronescu, C., Muhler, M., Schuhmann, W., Chen, YT.: A Universal Nano-capillary Based Method of Catalyst Immobilization for Liquid-Cell Transmission Electron Microscopy, Angewandte Chemie International Edition 2020. DOI: 10.1002/anie.201916419.
Terwey, A., Gruner, M.E., Keune, W., Landers, J., Salamon, S., Eggert, B., Ollefs, K., Brabänder, V., Radulov, I., Skokov, K., Faske, T., Hu, M.Y., Zhao, J., Alp, E.E., Giacobbe, C., Gutfleisch, O., Wende, H.: Influence of hydrogenation on the vibrational density of states of magnetocaloric LaFe_11.4Si_1.6H_1.6, Physical Review B 2020. DOI: 10.1103/PhysRevB.101.064415.
Waffel, D., Budiyanto, E., Porske, T., Büker, J., Falk, T., Fu, Q., Schmidt, S., Tüysüz, H., Muhler, M., Peng, BX.: Investigation of Synergistic Effects between Co and Fe in Co_3-xFe_xO₄ Spinel Catalysts for the Liquid-Phase Oxidation of Aromatic Alcohols and Styrene, Molecular Catalysis 2020, 498, 111251. DOI: 10.1016/j.mcat.2020.111251.
Weiss, S., Ertl, M., Varhade, S.D., Radha, A.V., Schuhmann, W., Breu, J., Andronescu, C.: Trivalent iron rich CoFe layered oxyhydroxides for electrochemical water oxidation, Electrochimica Acta 2020. DOI: 10.1016/j.electacta.2020.136256.
Yildiz, C., Kutonova, K., Oßwald, S., Titze-Alonso, A., Bitzer, J., Bräse, S., Kleist, W.: Post-synthetic Modification of DUT-5-based Metal Organic Frameworks for the Generation of Single-site Catalysts and their Application in Selective Epoxidation Reactions, ChemCatChem 2020. DOI: 10.1002/cctc.201901434.
Yu, M., Moon, G., Castillo, R., Weidenthaler, C., DeBeer, S., Tüysüz, H.: Dual Role of Silver Moieties Coupled with Ordered Mesoporous Cobalt Oxide towards Electrocatalytic Oxygen Evolution Reaction, Angewandte Chemie International Edition 2020. DOI: 10.1002/anie.202003801.
Zhang, SY., Hajiyani, H., Hufnagel, A.G., Kampmann, J., Breitbach, B., Bein, T., Fattakhova-Rohlfing, D., Pentcheva, R., Scheu, C.: Sn-Doped Hematite for Photoelectrochemical Water Splitting: The Effect of Sn Concentration, Zeitschrift für Physikalische Chemie 2020, 234 (4), 683-698. DOI: 10.1515/zpch-2019-1482.
Zerebecki, S., Reichenberger, S., Barcikowski, S.: Continuous-Flow Flat Jet Setup for Uniform Pulsed Laser Postprocessing of Colloids, Journal of Physical Chemistry A 2020, 124, 52, 11125-11132. DOI: 10.1021/acs.jpca.0c08787.
Ziefuss, A.R., Haxhiaj, I., Müller, S., Gharib, M., Gridina, O., Rehbock, C., Chakraborty, I., Peng, BX., Muhler, M., Parak, W.J., Barcikowski, S., Reichenberger, S.: Origin of Laser-Induced Colloidal Gold Surface Oxidation and Charge Density, and Its Role in Oxidation Catalysis, Journal of Physical Chemistry C 2020, 124 (38), 20981-20990. DOI: 10.1021/acs.jpcc.0c06257.

2019

Aiyappa, H.B., Wilde, P., Quast, T., Masa, J., Andronescu, C., Chen, Y.T., Muhler, M., Fischer, R.A., Schuhmann, W.: Oxygen evolution electrocatalysis of a single MOF‐derived composite nanoparticle on the tip of a nanoelectrode, Angewandte Chemie International Edition 2019, DOI: 10.1002/anie.201903283
Alkan, B., Cychy, S., Varhade, S., Muhler, M., Schulz, C., Schuhmann, W., Wiggers, H., Andronescu, C.: Spray‐Flame‐Synthesized LaCo_1−xFe_xO₃ Perovskite Nanoparticles as Electrocatalysts for Water and Ethanol Oxidation, ChemElectroChem 2019, 6, 1-10.
Angel, S., Neises, J., Dreyer, M., Ortega, K.F., Behrens, M., Wang, Y., Arandiyan, H., Schulz, C., Wiggers, H.: Spray‐flame synthesis of La(Fe, Co)O₃ nano‐perovskites from metal nitrates, AIChE Journal 2019, https://doi.org/10.1002/aic.1674
Anke, S., Bendt, G., Sinev, I., Hajiyani, H., Antoni, H., Zegkinoglou, I., Jeon, H., Pentcheva, R., Roldan Cuenya, B., Schulz, S., Muhler, M.: Selective 2‑Propanol Oxidation over Unsupported Co₃O₄Spinel Nanoparticles: Mechanistic Insights into Aerobic Oxidation of Alcohols, ACS Catalysis 2019, 9, 5974-5985.
Barwe, S., Andronescu, C., Engels, R., Conzuelo, F., Seisel, S., Wilde, P., Chen, Y.T., Masa, J., Schuhmann, W.: Cobalt metalloid and polybenzoxazine derived composites for bifunctional oxygen electrocatalysis, Electrochimica Acta 297, 1042-1051.
Bergmann, A., Roldan Cuenya, B.: Operando Insights into Nanoparticle Transformations during Catalysis, ACS Catalysis 2019, 9, 11, 10020–10043. DOI: 10.1021/acscatal.9b01831.
El Arrassi, A., Liu, Z., Evers, M.V., Blanc,N., Bendt, G., Saddeler, S., Tetzlaff, D., Pohl, D., Damm, C., Schulz, S., Tschulik, K.: Intrinsic Activity of Oxygen Evolution Catalysts Probed at Single CoFe₂O₄ Nanoparticles, Journal of the American Chemical Society 2019, https://doi.org/10.1021/jacs.9b04516
Hu, YZ., Zhao, GX., Pan, QS., Wang, HH., Shen, ZW., Peng, BX., Busser, G.W., Wang, XK., Muhler, M.: Highly Selective Anaerobic Oxidation of Alcohols Over Fe-doped SrTiO₃ Under Visible Light, ChemCatChem 2019, 11, 5139–514. DOI: 10.1002/cctc.201901451.
Masa, J., Schuhmann, W.: The Role of Non-Metallic and Metalloid Elements on the Electrocatalytic Activity of Cobalt and Nickel Catalysts for the Oxygen Evolution Reaction, ChemCatChem 2019, DOI: 10.1002/cctc.201901151
Medina, D., Barwe, S., Masa, J., Seisel, S., Schuhmann, W., Andronescu, C.: Optimizing the synthesis of Co/Co-Fe nanoparticles/N-doped carbon composite materials as bifunctional oxygen electrocatalysts, Electrochimica Acta 2019, 318, 281-289, DOI: 10.1016/j.electacta.2019.06.048
Reichenberger, S., Marzun, G., Barcikowski, S., Muhler, M.: Perspective of surfactant‐free colloidal nanoparticles in heterogeneous catalysis, ChemCatChem 2019, https://doi.org/10.1002/cctc.201900666
Tarnev, T., Aiyappa, H.B., Botz, A., Erichsen, T., Ernst, A., Andronescu, C., Schuhmann, W.: Scanning electrochemical cell microscopy investigation of single ZIF‐derived nanocomposite particles as electrocatalysts for oxygen evolution in alkaline media, Angewandte Chemie International Edition, 2019, 58, 14265-14269, DOI: 10.1002/anie.201908021
Waffel, D., Alkan, B., Fu, Q., Chen, Y.-T., Schmidt, S., Schulz, C., Wiggers, H., Muhler, M., Peng, BX.: Towards Mechanistic Understanding of Liquid-Phase Cinnamyl Alcohol Oxidation with tert-Butyl Hydroperoxide over Noble-Metal-Free LaCo_1–xFe_xO₃ Perovskites, ChemPlusChem 2019, 84, 1155–1163, https://onlinelibrary.wiley.com/doi/full/10.1002/cplu.201900429
Wang, S., Bendt, G., Saddeler, S., Schulz, S.: Synergistic Effects of Mo₂C‐NC@Co_xFe_y Core–Shell Nanoparticles in Electrocatalytic Overall Water Splitting Reaction, Energy Technology 2019, 7, DOI: 10.1002/ente.201801121.
Xu, Y., Ozcan, F., Zielke, P., Becker, S., Heimann, M., Heese, J., Chakrapani, K., Behrens, M., Simonsen, S.B., Norby, P., Hendriksen, P.V., Kiebach, R.: Continuous Hydrothermal Flow Synthesis of Co_1-xNi_xFe₂O₄ (x=0-0.8) Nanoparticles and Their Catalytic Properties for CO Oxidation and Oxygen Evolution Reaction, ZAAC 2019, 644, 24, 1727-1733. DOI: 10.1002/zaac.201800307
Yu, M., Waag, F., Chan, C., Weidenthaler, C., Barcikowski, S., Tüysüz, H.: Laser fragmentation induced cobalt oxide nanoparticles for electrochemical oxygen evolution reaction, ChemSusChem 2019, 12, 1-10, http://dx.doi.org/10.1002/cssc.201903186

Collaborative Research Centre / Transregio 247

Heterogeneous Oxidation Catalysis in the Liquid Phase (1st funding period 2018-2022)